And RAID1 + RAID1 to RAID 10
RAID1 to RAID10 yes but not RAID1 + RAID1 to RAID10.
I'm sure I could help you speed up the process (USB3->NAS vs NAS<->LAN<->PC+RAID migration) but please do proceed with your plan and I hope all goes well, do let us know.
I have/had an active webserver for educational purposes, Emby and Roon running.
I'm running a few sites and there's few users login remotely so I can't turn off the NAS. I ran my custom monitoring to find any rogue process trying to wake the disks while they're supposed to be asleep, not the 5mins diagnostics tool provided by Asustor which to me doesn't provide any relevant info but I do find the hibernate log useful. I do this whenever I notice the disks are not hibernating. It could take analyzing a whole day worth of logs just to pin the issue, could be a recently updated apps or ADM itself.
From what I experienced, the disks will never sleep or NAS enter S3 as long as there's apps actively running off the internal disks. Not only apps, the OS and SWAP also resides on the same data volume disks only on different partitions. The reason why I moved the OS to the external SSD and turned off SWAP completely.